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物理無機化學 Physical Inorganic Chemistry |
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1.
B.
S., National Chung Hsing University (1976) 2.
M.
S., National Tsing-Hua University (1978) 3.
Ph.
D., Case Western Reserve University (1985) 4.
Associate
Professor, National Chung Hsing University (1985-1989) 5.
Professor,
National Chung Hsing University (1989- ) |
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本實驗室研究的範圍主要是合成及鑑定 Ga,In, Tl, Fe, Sn之 porphyrin,並選擇軸向 ligand 如OAc-當其接上此類金屬,可能進行分子間交換。我們試著用 NMR及 EPR法來了解其機構,並求得其動力參數。 |
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Our research mainly
involves the synthesis and characterization of the transition metal complex
made from the coordination of metal (Ga, In, Tl, Fe, Sn)
with the porphyrin. We especially
interests in the ligand (i.e. acetate) axially coordinated to the central
metal with the property of undergoing the intermolecular ligand
exchange. Dynamical NMR and EPR
provide a route to evaluate the related kinetic parameters. |
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1. Yu-Cheng Wang, Jyh-Horung
Chen*, Shin-Shin Wang, Jo-Yu Tung, Unusual Inner
C-Alkylation of 2-N-Substituted N-Confused Porphyrin Cobalt Complexes in
Toluene and p-Xylene, Inorg. Chem. 2013, 52,
10711-10713. 2. Shin-Shin Wang,
Sui-Hui Wu, Jyh-Horung Chen, A Simple
Printable Etchant Formulation For Etching Oxidic,
Transparent and Conductive Layers, IEEE
Xplore, 2013,
113-115. 3. Yu-Cheng Wang, Ming-Yu Chen, Hong-Yi
Wu, Jyh-Horung Chen*, Shin-Shin Wang,
Jo-Yu Tung*, Pt(II) 2-N substituted
N-confused porphyrin: Pt(2-NCH2COOCH2C6H5NCTPP),
Pt(2-NCH2-p-C6H4CNNCTPP)
and Pt(2-NCH2-p-C6H4CF3NCTPP),
Polyhedron. 2014, 67, 73-80. 4. Yu-Cheng Wang, Jyh-Horung
Chen*, Shin-Shin Wang, Jo-Yu Tung, Metal complexes of
2-aza-2-benzyloxycarbonylmethyl-5,10,15,20-tetraphenyl-21-carbaporphyrin:
M(2-NCH2COOCH2C6H5NCTPP) (M = Ni2+,
Pd2+) and Mn(2-NCH2COOCH2C6H5NCTPP)Br
(NCTPP = N-confused 5,10,15,20-tetraphenylporphyrinate), Polyhedron. 2014,
68, 23-31. 5.
Chun-Chia Chiu , Jyh-Horung Chen* , Shin-Shin Wang, Jo-Yu
Tung, Magnetic susceptibility
and EPR spectra of Co(II) 2-N substituted N-confused porphyrin: Co(2-NCH2-p-C6H4-isoC3H7-21-CH2-p-C6H4CH3-NCTPP)Cl, Polyhedron. 2014, 83, 212-219. 6. Ya-Yuan
Lai, Yu-Chang
Chang, Jyh-Horung Chen*, Shin-Shin Wang, and Jo-Yu Tung, Axial zero-field splitting in
mononuclear Co(II) 2-N substituted N-Confused porphyrin: Co(2-NC3H5-21-Y-CH2C6H4CH3-NCTPP)Cl
(Y = o, m, p) and Co(2-NC3H5-21-CH2C6H5-NCTPP)Cl,
Dalton Trans. 2016, 45, 4854-4862. 7. Hsiang-Yin Lin, Chun-Yeh Lin, Chun-Chia
Chiu, Hsueh-Ju Li, Jyh-Horung Chen, Shin-Shin Wang, Jo-Yu Tung*, Weak η2–C–H…Hg interactions. Crystal
structures of Hg(II) 2-N substituted N-confused
porphyrin : Hg(2-NCH2-p-C6H4-CH3-21-H-NCTPP)I
and Hg(2-NCH2-p-C6H4-isoC3H7-21-H-NCTPP)I
• C6H5CH3, Polyhedron. 2017, 130, 30-39. 8. Chun-Yeh Lin,
Jyh-Horung Chen *, Jo-Yu
Tung*, Molecular structures of cobalt complexes of 2-aza-2-[p-methylbenzyl]-5,10,15,20-tetraphenyl-21-carbaporphyrin
: [Co(2-NCH2-p-C6H4CH3-21-m-CH2C6H4CH3NCTPP)L]
(L = Cl-, N*CS-) , Polyhedron. 2018, 139, 237-242. |
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國立中興大學化學系National
Chung Hsing University Department of Chemistry 地址:台中市國光路250號 化學館 電話:04-22840411 傳真:04-22862547 |
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