jyhhchen@dragon.nchu.edu.tw

物理無機化學

Physical Inorganic Chemistry

1. B. S., National Chung Hsing University (1976)

2. M. S., National Tsing-Hua University (1978)

3. Ph. D., Case Western Reserve University (1985)

4. Associate Professor, National Chung Hsing University (1985-1989)

5. Professor, National Chung Hsing University (1989- )

本實驗室研究的範圍主要是合成及鑑定 Ga，In， Tl， Fe， Sn之 porphyrin，並選擇軸向 ligand 如OAc-當其接上此類金屬，可能進行分子間交換。我們試著用 NMR及 EPR法來了解其機構，並求得其動力參數。

Our research mainly involves the synthesis and characterization of the transition metal complex made from the coordination of metal (Ga, In, Tl, Fe, Sn) with the porphyrin. We especially interests in the ligand (i.e. acetate) axially coordinated to the central metal with the property of undergoing the intermolecular ligand exchange. Dynamical NMR and EPR provide a route to evaluate the related kinetic parameters.

( 2013-2017)

1. Yu-Cheng Wang, Jyh-Horung Chen*, Shin-Shin Wang, Jo-Yu Tung, Unusual Inner C-Alkylation of 2-N-Substituted N-Confused Porphyrin Cobalt Complexes in Toluene and p-Xylene, Inorg. Chem. 2013, 52, 10711-10713.

2. Shin-Shin Wang, Sui-Hui Wu, Jyh-Horung Chen, A Simple Printable Etchant Formulation For Etching Oxidic, Transparent and Conductive Layers, IEEE Xplore, 2013, 113-115.

3. Yu-Cheng Wang, Ming-Yu Chen, Hong-Yi Wu, Jyh-Horung Chen*, Shin-Shin Wang, Jo-Yu Tung*, Pt(II) 2-N substituted N-confused porphyrin: Pt(2-NCH₂COOCH₂C₆H₅NCTPP), Pt(2-NCH₂-p-C₆H₄CNNCTPP) and Pt(2-NCH₂-p-C₆H₄CF₃NCTPP), Polyhedron. 2014, 67, 73-80.

4. Yu-Cheng Wang, Jyh-Horung Chen*, Shin-Shin Wang, Jo-Yu Tung, Metal complexes of 2-aza-2-benzyloxycarbonylmethyl-5,10,15,20-tetraphenyl-21-carbaporphyrin: M(2-NCH₂COOCH₂C₆H₅NCTPP) (M = Ni²⁺, Pd²⁺) and Mn(2-NCH₂COOCH₂C₆H₅NCTPP)Br (NCTPP = N-confused 5,10,15,20-tetraphenylporphyrinate), Polyhedron. 2014, 68, 23-31.

5. Chun-Chia Chiu , Jyh-Horung Chen* , Shin-Shin Wang, Jo-Yu Tung, Magnetic susceptibility and EPR spectra of Co(II) 2-N substituted N-confused porphyrin: Co(2-NCH₂-p-C₆H₄-isoC₃H₇-21-CH₂-p-C₆H₄CH₃-NCTPP)Cl, Polyhedron. 2014, 83, 212-219.

6. Ya-Yuan Lai, Yu-Chang Chang, Jyh-Horung Chen*, Shin-Shin Wang, and Jo-Yu Tung, Axial zero-field splitting in mononuclear Co(II) 2-N substituted N-Confused porphyrin: Co(2-NC₃H₅-21-Y-CH₂C₆H₄CH₃-NCTPP)Cl (Y = o, m, p) and Co(2-NC₃H₅-21-CH₂C₆H₅-NCTPP)Cl, Dalton Trans. 2016, 45, 4854-4862.

7. Hsiang-Yin Lin, Chun-Yeh Lin, Chun-Chia Chiu, Hsueh-Ju Li, Jyh-Horung Chen, Shin-Shin Wang, Jo-Yu Tung^*, Weak η²–C–H^…Hg interactions. Crystal structures of Hg(II) 2-N substituted N-confused porphyrin : Hg(2-NCH₂-p-C₆H₄-CH₃-21-H-NCTPP)I and Hg(2-NCH₂-p-C₆H₄-isoC₃H₇-21-H-NCTPP)I • C₆H₅CH₃, Polyhedron. 2017, 130, 30-39.

8. Chun-Yeh Lin, Jyh-Horung Chen ^*, Jo-Yu Tung^*, Molecular structures of cobalt complexes of 2-aza-2-[p-methylbenzyl]-5,10,15,20-tetraphenyl-21-carbaporphyrin : [Co(2-NCH₂-p-C₆H₄CH₃-21-m-CH₂C₆H₄CH₃NCTPP)L] (L = Cl^-, N*CS^-) , Polyhedron. 2018, 139, 237-242.

國立中興大學化學系National Chung Hsing University Department of Chemistry

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