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fehong@dragon.nchu.edu.tw

無機化學/有機金屬化學

Inorganic Chemistry /Organometallic Chemistry

 

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1.         B. S., National Tsing Hua University (1979)

2.         Ph. D., University of Notre Dame (1988)

3.         Postdoctoral Fellow, The Ohio State University (1988-1990)

4.         Associate Professor, National Chung Hsing University (1990-1995)

5.         Professor, National Chung Hsing University (1995-)

6.         Chair, Chemistry Department, National Chung Hsing University (2004-2007)

7.         Lifetime Chair Professor (2018)

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本實驗室目前的研究範圍主要集中在開發一些新型態的有機金屬多牙配位基及一些相關的衍生物。這些有機金屬多牙基可被應用於一些有機物化合物的耦合催化反應中充當配位基的角色,的確展現一些和傳統有機配位基不同的特性,催化反應上也有其獨特的效果。近來,我們也利用耦合反應的技巧來修飾一些具螢光特性及生物毒性之有機物,應用於生物影像及生物毒性之實驗。

除此之外,我們利用量子力學計算方式來幫助及彌補傳統實驗方法在了解化學反應機制上的不足。特別是針對在實驗中所發現的一些不尋常的現象及結果做反應途徑的理論探討。這方式的確提供相當深入且有用的資訊。

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We have been interested in the topic of catalytic property studies of some unconventional metal-containing chelating ligands.  These ligands have been employed in the palladium assisted coupling reactions toward some designated organic compounds.

Recently, we also involved in the studies of the fluorescence emission and cytotoxic nature of some biologically active organic molecules. Modification of these compounds by employing the techniques of coupling reactions furnished new synthesized compounds with enhanced physical and chemical properties.

Moreover, theoretical studies employed quantum calculation methods have been implemented on some particular mechanistic problems which had been encountered in catalytic reactions. Computational calculations provide us with useful and valuable information in terms of clarifying the reaction pathways.

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Selected Publications (2001~2022):

(A)      期刊論文

75. Incorporation of Norbornene or Dicyclopentadiene Moiety onto Naphthoquinone-containing Pyrroles through Transition metal Catalyzed C-H or N-H Bond Activation, Chiao-Yun Chang and Fung-E Hong*, J. Organomet. Chem. 2022. DOI: 10.1016/j.jorganchem.2022.122253

74. Palladium Catalyzed Carbon-Hydrogen Bond Activation on Amino-substituted Quinones under Acidic Condition, Peng-Hao Huang, Rui-Yu Hong, and Fung-E Hong*, J. Chin. Chem. Soc. 2021, 68, 2337-2347.

73. Formations of aryl or pyrrole rings via palladium-catalyzed C-H functionalization on amido-substitued quinones in the presence of amines or phosphines, Cang-Sian Li, Yi-Ping Tseng, Ting-Hsuan Hsu, Chiao-Yun Chang, Fung-E Hong*, J. Chin. Chem. Soc. 2021, 68, 682-694.

72. Tertiary amines as vinyl source for the formations of aryl or pyrrole ring on amido-substitued 1,4-quinone with the assistance of palladium salt, Jia-Nan Jhou, Chiu-Wen Cheng and Fung-E Hong*, J. Chin. Chem. Soc. 2020, 67, 2118-2128.

71. Palladium-Catalyzed Phosphination and Amination through C-H Bond Functionalization on Biphenyl: Amido-substituent as Directing Group, I-Hsiang Kao, Ching-Yu Wang, Yu-Chang Chang, Chu-Lun Wu, Yu-Jen Chiu, and Fung-E Hong*, Tetrahedron, 2019, 75, 387-397.

70. Incorporation of Norbornene Moiety onto the Arene of Diaryl Substituted Amides through C-H Functionalization, Hsueh-Min Chou, Jia-Nan Jhou, Fung-E Hong*, J. Organmet. Chem. doi.org/10.1016/j.jorganchem.2017.10.041.

69. Palladium-Catalyzed C-H Functionalization of Amido-substitued 1,4-Napthoquinone in the Presence of Amines Toward the Formation of Pyrroles and Imidazoles, Szu-Wei Chen, Fung-E Hong*, ChemistrySelect, DOI: 10.1002/slct.201702173.

68. Making C-N and C-P Bonds on the Quinone Derivatives Through the Assistance of Silver-mediated C-H Functionalization Processes, Pin-Ting Yuan, Ching-Hua Pai, Shi-Zong Huang, and Fung-E Hong*, Tetrahedron, DOI: 10.1016/j.tet.2017.10.037.

67. Secondary Phosphine Oxides Assisted Palladium Complexes Catalyzed Catellani Reaction for the Formation of Carbazole Derivatives, Ya-Chan Chen, Hsueh-Min Chou, I-Hsiang Kao, Yu-Chang Chang, and Fung-E Hong*, J. Organmet. Chem. 2017, 846, 389-396.

66. The C-H Bond Functionalization of 1,4-Benzoquinone by Silver-mediated Regioselective Phosphination and Amination Reactions, Yu-Chang Chang, Pin-Ting Yuan and Fung-E Hong*, Eur. J. Org. Chem. 2017, 2441-2450.

65. Preparations of Secondary Phosphine Oxide Ligands through Nucleophilic Attack on Imines and Their Applications in Palladium Catalyzed Catellani Reactions, Chan-Yu Hu, Ya-Qian Chen, Guan-Yu Lin, Ming-Kai Huang, Yu-Chang Chang, Fung-E Hong*, Eur. J. Inorg. Chem. 2016, 3131-3142.

64. Preparations of Saturated N-P-N Type Secondary Phosphine Oxides and their Applications in Cross-Coupling Reactions, Yu-Chang Chang, Ya-Han Liang, and Fung-E Hong*, J. Chin. Chem. Soc. 2016, 63, 353-367.

63. Heteroatom-Substituted Secondary Phosphine Oxides for Suzuki-Miyaura Cross-coupling Reactions, Yu-Chang Chang, Yi-Chang Lee, Meng-Fan Chang, Fung-E Hong*, J. Organomet. Chem. 2016, 808, 23-33.

62. Computational and 31P NMR Studies of Moisture-metastable Cyclic Diaminophosphine Oxide Preligands, Yu-Chang Chang, Chan-Yu Hu, Ya-Han Liang, and Fung-E Hong*, Polyhedron, 2016, 105, 123-136.

61. Recent Developments in the Preparation of N-heterocycles using Pd-Catalyzed C-H Activation, Tanveer MahamadAli Shaikh* and Fung-E Hong*, J. Organomet. Chem. 2016, 801, 139-156.

60. Developing Five-membered Heterocycle Substituted Phosphinous Acids as Ligands for Palladium-Catalyzed Suzuki-Miyaura and Catellani Reactions, Ting-Wei Chang, Pei-Yun Ho, Kuo-Chung Mao, and Fung-E Hong*, Dalton Trans., 2015, 44, 17129-17142.

59. Imidazolio-substituted Secondary Phosphine Oxides as Potential Carbene Reagents, Yu-Chang Chang, Chih-Hung Chang, Lyu-Wei Wang, Ya-Han Liang, Dan-Fu Hu, Chia-Ming Weng, Kuo-Chung Mao, and Fung-E Hong*, Polyhedron, 2015, 100, 382-391.

58. Catellani type N-H activation of indole derivatives and resolution of palladium complexes containing norbornene or dicyclopentadiene moieties, Ya-Qian Chen, Fung-E Hong*, Tetrahedron, 2015, 71, 7016-7025. (NSC 101-2113-M-005-011-MY3)

57. Magnesium Halide-Promoted Ring-opening Reaction of Cyclic Ether in the Presence of Phosphine Halide, Yu-Chang Chang, Chia-Ming Weng, Tanveer M. Shaikh and Fung-E Hong*, J. Chin. Chem. Soc. 2015, 62, 703-711. (NSC 101-2113-M-005-011-MY3)

56. Alkyl(quinolin-8-yl)phosphine Oxides as Hemilabile Preligands for Palladium-Catalyzed Reactions, Yu-Chang Chang, Wei-Chan Chang, Chan-Yu Hu, and Fung-E Hong*, Organometallics, 2014, 33, 3523-3534.

55. Efficient Method for the Oxidation of Aldehydes and Diols with tert-Butylhydroperoxide under Transition Metal-Free Conditions, Tanveer Mahammadali Shaikh and Fung-E Hong, Tetrahedron, 2013, 69, 8929-8935. (NSC 101-2113-M-005-011-MY3)

54. Palladium(II)-catalyzed Heck reaction of aryl halides and arylboronic acids with olefins under mild conditions, Tanveer Mahamad Ali Shaikh and Fung-E Hong*, Beilstein J. Org. Chem. 2013, 9, 1578-1588. (NSC 101-2113-M-005-011-MY3)

53. Preparation and Application of Indolyl Secondary Phosphine Oxides in Palladium Complexes Catalyzed Suzuki-Miyaura Cross-coupling Reaction, Yen-Yu Chang and Fung-E Hong*, Tetrahedron, 2013, 69, 2327-2335. (NSC 98-2113-M-005-006-MY3)

52. Secondary Phosphine Oxides: a Versatile Ligands in Transition Metal-Catalyzed Cross-coupling Reactions, Tanveer Mahamadali Shaikh, Chia-Ming Weng, and Fung-E Hong*, Coord. Chem. Rev. 2012, 256, 771-803.

51. DFT Studies on Ferrocenyl or Cobaltocenyl Phosphines Ligated Palladium Complexes Catalyzed Suzuki-Miyaura Reactions, Jun Hsiao, Chia-Ming Weng and Fung-E Hong*, J. Chin. Chem. Soc. 2012, 59, 161-169.

50. DFT Studies on the Reaction of CpCo(PPh3)2 with Diphenylphosphinoalkynes: Formation of Cobaltacycles and Cyclobutadiene-Substituted CpCoCb Diphosphines, Chia-Ming Weng and Fung-E Hong*, Organometallics, 2011, 30, 3740-3748.

49. Density Functional Studies on Diimine Chelated Palladium Complex Catalyzed Suzuki-Miyaura Cross-Coupling Reaction: The Impact of Lewis Base Employed in Transmetallation Process, Chia-Ming Weng, Fung-E Hong*, Dalton Trans. 2011, 40, 6458-6468.

48. Iron-Catalyzed Oxidative Cleavage of Olefins and Alkynes to Carboxylic Acids with TBHP in aq. Medium, Tanveer Mahamadali Shaikha and Fung-E Hong*, Adv. Synth. Catal. 2011, 353, 1491-1496.

47. Preparation of New Buchwald Type Secondary Phosphine Oxide Ligands and Applications in Suzuki-Miyaura Reactions, Dan-Fu Hu, Chia-Ming Weng and Fung-E Hong*, Organometallics, 2011, 30, 1139-1147.

46. Preparation of cobalt-containing ligands with NHC- and/or P-coordinating sites and their applications in Heck reaction: The formation of an unexpected cobalt-containing zwitterionic complex, Chi-Shing Guo, Chia-Ming Weng, and Fung-E Hong*, Eur. J. Inorg. Chem. 2010, 3220-3228.

45. Preparation of Cobalt Sandwich Diphosphine Ligand [(h5-C5H4iPr)Co(h4-C4(PPh2)2Ph2)] and its Chelated Palladium Complex: Application of Diphosphine Ligand in the Preparation of Mono-substituted Ferrocenylarenes, Chin-Pei Chang, Chia-Ming Weng and Fung-E Hong*, Inorg. Chim. Acta, 2010, 363, 412-417.

44. Application of Tautomerism of Ferrocenyl Secondary Phosphine Oxides in Suzuki-Miyaura Cross Coupling Reactions, Lin-Ying Jung, Shih-Hung Tsai and Fung-E Hong*, 2009, Organometallics, 28, 6044-6053.

43. ((2-Benzothiazol-2-yl-hydrazonomethyl)- 6-methoxy-phenol-kN,kN, m2-O,kO)- (methanol-kO)-(nitrate-kO)- ((2-benzothiazol-2-yl-hydrazonomethyl)- 6-methoxy-phenol-kN,kN,kO)- di-copper(II) nitrate, Yu-Ching Lin and Fung-E Hong*, 2009, Acta Cryst. E., E65, m1077.

42. Bis[1,3(h3)-allyl] [l-2(h4)-1,3-bis(diphenylphosphino)- 2,4- diphenylcyclobuta- 1,3-diene-1:3k2P:P’] dichlorido-1kCl,3kCl- [2(h5)-isopropylcyclopentadienyl]- 2-cobalt(I)-1,3-dipalladium(II) dichloromethane solvate, Chin-Pei Chang and Fung-E Hong*, 2009, Acta Cryst. E65, m669.

41. Synthesis of coumarin derivatives by palladium complex catalyzed intramolecular Heck reaction: Preparation of a 1,2-cyclobutadiene-substituted CpCoCb diphosphine chelated palladium complex, Chin-Pei Chang, Santhanakrishnan V. Pradiuldi and Fung-E Hong*, 2009, Inorg. Chem. Comm., 2009, 12, 596-598.

40. Preparation of a cobalt-containing P,N-bidentate ligand ligated palladium complex: Its applications in Amination and Suzuki cross coupling reactions, Wen-Yuan Chiang and Fung-E Hong*, J. Organomet. Chem., 2009, 694, 1473-1481.

39. Convenient and Efficient Suzuki-Miyaura Cross-Coupling Reactions Catalyzed by N,N,O-Tridentate Ligands Ligated Palladium Complexes, Siddappa A. Patil, Chia-Ming Weng, Po-Cheng Huang and Fung-E Hong*, Tetrahedron, 2009, 65, 2889-2897.

38. Amination and Suzuki coupling reactions catalyzed by cobalt-containing monodentate phosphines with bis-trifluoromethyl substituents on bridged arylethynyl: Observation of some unusual metal-containing compounds, Po-Cheng Huang and Fung-E Hong*, J. Organomet. Chem., 2009, 694, 113-121.

37. Preparation and characterization of cobalt-containing PÇN ligands and an unusual palladium complex ion pair: Their applications in amination reactions, You-Chen Hsiao, Wen-Yuan Chiang, Chia-Ming Weng and Fung-E Hong*, Tetrahedron, 2008, 64, 9507-9514.

36. Preparations of Cobalt-Containing Bulky Monodentate Phosphines with Electron-Withdrawing/Donating Substituents on Arylethyne: Their Applications in Suzuki Coupling Reactions, Bo-Yuan Shiu, Po-Cheng Huang, Yi-Luen Huang and Fung-E Hong*, Tetrahedron, 2008, 64, 6221-6229.

35. Density Functional Studies on Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions Assisted by N- or P-Chelating Ligands, Yi-Luen Huang, Chia-Ming Weng, Fung-E Hong*, Chem. Eur. J., 2008, 14, 4426-4434.

34. Preparation of Monodentate Phosphinite Ligands: Their Applications in Palladium Catalyzed Suzuki Reactions, Yan-Huei Cheng, Chia-Ming Weng and Fung-E Hong*, Tetrahedron, 2007, 63, 12277-12285.

33. Preparation and Characterization of Cobalt-Containing Alcohols and Diols, Jian-Cheng Lee, Yu-Chang Chang, Yi-Jung Ho, Kang-Ming Chu, Hsueh-Liang Chen and Fung-E Hong*, Polyhedron, 2007, 26, 2987-2996.

32. Experimental and DFT Study of the Tautomeric Behavior of a Cobalt-containing Secondary Phosphine Oxide, Chu-Hung Wei, Cheng-En Wu, Yi-Luen Huang, Roman G. Kultyshev, and Fung-E Hong* , Chem. Eur. J., 2007, 13, 1583-1593.

31. Preparation of a Palladium Dimmer Having Cobalt-containing Bulky Phosphine Ligand: Its Application in Palladium Catalyzed Suzuki Reactions, Ya-Huei Gan, Jian-Cheng Lee and Fung-E Hong*, Polyhedron, 2006, 25, 3555-3561.

30. Reaction of CpCo(PPh3)2 with Diphenylphosphinoalkynes: Syntheses and X-Ray Structures of 1,3-Cyclobutadiene-Substituted CpCoCb Diphosphine and 2,5-Cobaltacyclopentadiene Diphosphine Dioxide, Chin-Pei Chang, Roman G. Kultyshev, Fung-E Hong*, J. Organomet. Chem., 2006, 691, 5843-5849.

29. Oxygen Insertion in a Carbon-Phosphorus Bond of the Di-tert-butyl-phenylethynyl-phosphane Bridged Dicobalt Complex: Exploring the Nature of Oxygen Migration with DFT Means, Yi-Luen Huang, Chin-Pei Chang, Fung-E Hong*, Dalton Trans., 2006, 5454-5463.

28. Preparation and Characterization of a Cobalt-containing Mono-Phosphine Ligand and Its Coordinated Molybedenum Complex, Yi-Luen Huang, Min-Ging Wang and Fung-E Hong*, J. Chin. Chem. Soc., 2006, 53, 1039-1044.

27. Density Functional Studies on Dicobalt Octacarbonyl Mediated Azobenzene Formation from 4-Ethynylaniline, Yi-Luen Huang and Fung-E Hong*, Chem. Eur. J., 2006, 12, 1403-1412.

26. Preparation and Characterization of a Novel Palladium Complex: cis-Dichloride(1,2-bis(diphenylphosphino)vinyl-P,P',C)palladium(II)(bis(diphenylphosphino)methane-P,P')cobaltacarbonyl, Chin-Pei Chang and Fung-E Hong*, J. Chin. Chem. Soc., 2005, 52, 1105-1109.

25. Design, Synthesis, and Application to Suzuki-Miyaura Reactions of a Dicobalt Carbonyl-Containing Phosphine Ligand: Exploring the Ligand's Nature with NMR and DFT Means, Yu-Chang Chang and Fung-E Hong*, Organometallics, 2005, 24, 5686-5695.

24. Palladium Catalyzed Amination Reactions Using Cobalt-containing Bulky Phosphine Ligands, Jian-Cheng Lee, Ming-Gin Wang, Fung-E Hong, Eur. J. Inorg. Chem., 2005, 5011-5017.

23. Palladium Catalyzed Suzuki Cross-coupling Reactions Using N,O-Bidentate Ligands, Yi-Chun Lai, Hsuan-Ying Chen, Wen-Chou Hung, Chu-Chieh Lin, and Fung-E Hong*, Tetrahedron, 2005, 61, 9484-9489.

22. Biphasic Suzuki Coupling Reactions of Aryl or Benzyl Bromides Employing Cobalt-containing Phosphine Ligand Coordinated Palladium Complex, Chin-Pei Chang, Yi-Luen Huang, Fung-E Hong,* Tetrahedron, 2005, 61, 3835-3839.

21. Synthesis of Cobalt-Containing Monodentate Phosphine Ligand and Application Toward Suzuki Cross-Coupling Reactions, Fung-E Hong,* Yi-Jung Ho, Yu-Chang Chang and Yi-Luen Huang, J. Organomet. Chem., 2005, 690, 1249-1257.

20. Observations on Reaction Pathways of Dicobalt Octacarbonyl with Alkynyl Amines, Fung-E Hong*, Yi-Luen Huang and Hsueh-Liang Chen, J. Organomet. Chem., 2004, 689, 3449-3460.

19. Density Functional Studies on Dicobalt Octacarbonyl Mediated Urea Formation from Primary Amine, Fung-E Hong* and Yu-Chang Chang, Organometallics, 2004, 23, 718-729.

18. Palladium Catalyzed Suzuki Coupling Reactions Using Cobalt-Containing Bulky Phosphine Ligands, Fung-E Hong,* Yi-Jung Ho, Yu-Chang Chang, and Yi-Chun Lai, Tetrahedron, 2004, 60, 2639.

17. Density Functional Studies of [{Mo(h5-Cp)(CO)2}2(m-H)(m-PMe2)], [{Mo(h5-Cp)(CO)2}2(m-PMe2)]- and [{Mo(η5-Cp)(CO)3}2]: Do the Metal-Metal Bonds Exist? Fung-E Hong*, Yu-Chang Chang, Bull. Chem. Soc. Jpn., 2004, 77, 115-121.

16. Synthesis of Mono- and Tri-nuclear Ruthenium Carbonyl Complexes Containing the Pyridine-2-thiolato Ligand and Reactivity of a Bis(pyridine-2-thiolato) Chelated Ruthenium Dicarbonyl Complex with a Novel Cobalt-containing Diphosphine Ligand, Fung-E Hong,* Yu-Chang Chang, Shu-Chun Chen, Bull. Chem. Soc. Jpn., 2004, 77, 103-107.

15. Preparations and NMR Studies of Cobalt-Containing Di-Phosphine Ligand Chelated Tungsten, Ruthenium, Gold and Palladium Complexes: Suzuki Cross-Coupling Reactions and Carbonylation Catalyzed by Palladium Complex, Fung-E Hong,* Yu-Chang Chang, Chin-Pei Chang and Yi-Luen Huang, Dalton Trans, 2004, 157-165.

14. Syntheses and characterizations of group 6 metal cyanotrihydroborate complexes, Fu-Chen Liu, Yow-Chuan Sheu, Jo-Ju She, Yu-Chang Chang, Fung-E Hong, Gene-Hsian Lee, Shie-Ming Peng, J. Organomet. Chem., 2004, 689, 544-551.

13. Preparations of Cobalt-Containing Phosphines and Reactions toward Dicobalt Octacarbonyl, Fung-E Hong,* Yi-Chun Lai, Yi-Jung Ho, Yu-Chang Chang, J. Organomet. Chem., 2003, 688, 161-167.

12. Synthesis and Structural Characterization of Novel Palladium Complexes Chelated by Bulky Cobalt-Containing Phosphine Ligands: Unusual Palladium-Cobalt Bond Formations, Fung-E Hong,* Chin-Pei Chang, Yu-Chang Chang, Dalton Trans., 2003, 3892-3897.

11. Reactions of Sulfido-tricobalt Cluster (m3-S)Co3(CO)7(m-C,N-C5H4N) with Diphosphine Ligands and (m3-S)Co3(CO)7(m-S,P-SPMe2) Towards Diphenyl-2-pyridylphosphine, Fung-E Hong*, Chin-Pei Chang, Hao Chang, Yi-Luen Huang, and Yu-Chang Chang, J. Organomet. Chem. 2003, 677, 80.

10. Preparation and Characterization of Trimethylsilylpyridylacetylene Bridged, Dicobalt Carbonyl Complexes Containing Bis(diphenylphosphino)methylene or Bis(diphenylphosphino)ethylene Ligand, Fung-E Hong,* Cheng-Wei Chen, Yu-Chang Chang, and Yi-Luen Huang, J. Chin. Chem. Soc., 2003, 50, 973-978.

9.  Preparation and Characterization of Tricobalt Methylidyne Clusters; X-Ray Crystal Structures of [Co3(CO)9(m 3-CR)], {R: CH2CH3, CH2C(=O)NH2, CH2C(=O)CH3}, and [Co3(CO)7(m-P,P-PPh2CH2PPh2)(m3-CCH2C6H4NH2)], Fung-E Hong*, Yi-Luen Huang, Yu-Chang Chang, Kang-Ming Chu, and Yu-Tain Tsai, Appl. Organometal. Chem., 2003, 17, 458.

8.  A Novel Approach to the Synthesis of Azobenzene Using Dicobalt Carbonyl, Fung-E Hong*, Cheng-Wei Chen, Yu-Chang Chang, Dalton Trans, 2002, 2951.

7.  Formation of Alkyne Bridged Multicobalt Carbonyl Complexes with Tris(2-thienyl)phosphine or Bis(trimethylsilylethynyl)phenylphosphine Ligand, Fung-E Hong*, Fang-Ching Lien, Yu-Chang Chang, and Bao-Tsan Ko, J. Chin. Chem. Soc. 2002, 49, 509.

6.  Bis(diphenylphosphino)acetylene As Bi-functional Ligand In Dicobalt Carbonyl Complexes, Fung-E Hong*, Yu-Chang Chang, Ruei-E Chang, Shu-Chun Chen, and Bao-Tsan Ko, Organometallics, 2002, 21, 961.

5.  The reactions of 4,6-dimethyl-2-mercaptopyrimidine with dimetallic compounds: diiron nonacarbonyl and cyclopentadienylmolybedenum tricarbonyl dimer, Fung-E Hong*, Yi-Luen Huang, Pin-Pin Chen, Yu-Chang Chang, J. Organomet. Chem., 2002, 655, 49.

4.  Preparations of Sulfido-tricobalt Clusters Containing Pyridyl Type Ligands: Insertion of Carbon Monoxide into Cobalt-Carbon Bond, Fung-E Hong*, Shu-Chun Chen, Yu-Tain Tsai, Yu-Chang Chang, J. Organomet. Chem., 2002, 655, 172.

3.  Preparation and Characterization of Cyclic Compounds Consist of Bis(diphenylphosphino)acetylene or Bis(trimethylsilylacetyl)phenylphosphine Joined Alkyne-Bridged Dicobalt Fragments, Fung-E Hong*, Fang-Ching Lien, Hao Chang, Yu-Chang Chang, and Bao-Tsan Ko, Chem. Lett., 2001, 1130.

2.  Linking two alkyne-bridged dicobalt complexes via an urea-based ligand: synthesis, spectroscopic and structural characterization of {[Co2(CO)6(μ-HCC-)]-CH2NH}2C=O, Fung-E Hong*, Yu-Tain Tsai, Yu-Chang Chang, Bao-Tsan Ko, Inorg. Chem., 2001, 40, 5487.

1.  Preparation and characterization of an unusual tetracobalt-complex; X-ray crystal structure of [Co2(CO)5{m-P,P-(m-PPh2CºCPPh2)}][Co2(CO)4{m-P-(m-PPh2CºCPPh2)}], Fung-E Hong*, Hao Chang, Yu-Chang Chang, Bao-Tsan Ko, Inorg. Chem. Commun. 2001, 4, 723.

 

(B) 近五年研討會論文 (2015-2019)

1.  Silver-mediated C-H Functionalization of Benzoquinone in the Presence of Secondary Phosphine Oxides and Imines: The Formations of C-N and C-P Bonds, 252nd ACS National Meeting & Exposition, 2016/08/21-25, Philadelphia, Pennsylvania, PA, USA.

2.   Amido-group as a Directing Group in Palladium Catalyzed Carbon-hydrogen Bond Functionalization of Benzoquinone Derivatives, 28th International Conference on Organometallic Chemistry, 2018/07/15-20, Firenze, Italy.

3.   Amido-groups as Removable Directing Groups in Palladium Catalyzed Carbon-hydrogen Bond Functionalization of benzoquinone derivatives, 2019/07/14-18, 21st European Symposium on Organic Chemistry, Vienna, Austria.

4.   Pyrrole Ring Formation from the Amido-substituted Benzoquinone Derivatives via Palladium Catalyzed Carbon-hydrogen Bond Functionalization, 2019/09/01-06, 27th International Society of Heterocyclic Chemistry Congress, Kyoto, Japan.

5.   Consecutive Formations of Aryl and Pyrrole Rings via Palladium-Catalyzed C-H Functionalization on Amido-Substitued Diquinone in the Presence of Amines, 2019/12/08-12, 2019 Annual Meeting of Chinese Chemical Society Located in Taipei & 18th Asian Chemical Congress Conference, Taipei, Taiwan.

 

(C) 近五年演講

1.   Metal Catalyzed Carbon-hydrogen Bond Functionalization of Benzoquinone or Benzene Derivatives with Removable Directing Groups,暨南大學化學系,2017/05/19

2.   From Two Components Reactions to C-H Activation Reactions,靜宜大學化學系,2018/11/26

 

 

(D) 出版書籍:

1. 洪豐裕,《有機金屬化學》。國立中興大學出版中心,華藝學術出版社,2015/01出版。ISBN: 978-986-04-3583-2

2. 洪豐裕,《從解題著手懂普通化學》。國立中興大學出版中心,藝軒圖書出版社,2016/01出版。ISBN: 978-986-04-6903-5

3. 洪豐裕,《從解題著手懂配位化學》。國立中興大學出版中心,藝軒圖書出版社,2016/06出版。ISBN: 978-986-04-9030-5

4. 洪豐裕,《有機金屬化學解題良伴》。國立中興大學出版中心,思行文化傳播有限公司,2018/09出版。ISBN: 978-986-05-6333-7

5. 洪豐裕,《通識教育化學篇》。國立中興大學出版中心,思行文化傳播有限公司,2019/11出版。ISBN: 978-986-98378-7-3

 

Organometallic Chemistry_BookFront

《有機金屬化學》

《從解題著手懂普通化學》

配位化學01

《從解題著手懂配位化學》

有機金屬化學解題良伴封面#2

《有機金屬化學解題良伴》

通識教育化學篇_A

《通識教育化學篇》

 

國立中興大學化學系National Chung Hsing University Department of Chemistry

地址:台中市國光路250號 化學館 電話:04-22840411 傳真:04-22862547