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btko@dragon.nchu.edu.tw

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http://web.nchu.edu.tw/~btko/

柯寶燦

Bao-Tsan Ko

無機化學

Inorganic Chemistry

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l   Professor, National Chung Hsing University (2015-present)

l   Associate Professor, National Chung Hsing University (2013-2015)

l   Associate Professor, Chung Yuan Christian University (2011-2013)

l   Assistant Professor, Chung Yuan Christian University (2008-2011)

l   Manager, AssociateMaterial and Chemical Research Laboratories, Industrial Technology Research Institute (2005-2008)

l   Researcher, AssociateMaterial and Chemical Research Laboratories, Industrial Technology Research Institute (2002-2005)

l   Ph. D., Department of Chemistry, National Chung Hsing University (1998-2002)

l   M. S., Department of Chemistry, National Chung Hsing University (1996-1998)

l   B. S., Department of Chemistry, National Chung Hsing University (1992-1996)

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本實驗室之主要研究興趣為新穎金屬錯合物之設計、合成開發及結構鑑定,並將所開發之金屬錯合物作為製備聚酯(polyester)碳酸酯或聚碳酸酯之均相觸媒以及研究其催化特性。主要工作為:

一、新穎金屬錯合物的開發、鑑定及其催化應用。

二、活性聚合技術研究開發。

三、溫室氣體(CO2)再利用製作環境友善高分子材料。

高分子團聯共聚物的開發及應用。

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Our current research interests are mainly focusing on the design, synthetic development and structural characterization of novel metal complexes and to explore their applications in various catalytic reactions. The major works include:

1. Synthesis, characterization of novel metal complexes and their catalysis.

2. The developments of “living” polymerization.

3. Environmentally-friendly polymers prepared by ring-opening polymerization of cyclic esters or carbonates and CO2/epoxide copolymerization.

4.  Synthesis, characterization and application of block copolymers.

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(A)      期刊論文

(1)      Guan-Lin Liu, Hsin-Wei Wu, Zheng-Ian Lin, Min-Gan Liao, Yu-Chia Su, Chih-Kuang Chen* and Bao-Tsan Ko*, “Synthesis of functional CO2-based polycarbonates via dinuclear nickel nitrophenolate-based catalysis for degradable surfactant and drug-loaded nanoparticle applications”, Polym. Chem., 2021, 12, 1244–1259.

(2)      Yu-Chia Su and Bao-Tsan Ko*, “Alternating Copolymerization of Carbon Dioxide with Epoxides Using Highly Active Dinuclear Nickel Complexes: Catalysis and Kinetics”, Inorg. Chem., 2021, 60, 852–865.

(3)      Yu-Chia Su, Chi-Tien Chen, Bao-Tsan Ko*, “Catalysis and kinetics for alternating copolymerization of carbon dioxide with epoxides using dinuclear nickel catalysts of pyrazolyl based diamine-bisphenolate ligands”, Polymer 2020, 200, 122553.

(4)      Yu-Chia Su, Chih-Hsiang Tsui, Chen-Yen Tsai and Bao-Tsan Ko*, “Highly active bimetallic nickel catalysts for alternating copolymerization of carbon dioxide with epoxides”, Polym. Chem. 2020, 11, 3225–3236.

(5)      Ming-Han Li, Guan-Lin Liu, Yu-Chia Su, Bao-Tsan Ko*, “Nickel-catalyzed copolymerization of carbon dioxide with internal epoxides by di-nuclear bis(benzotriazole iminophenolate) complexes”, Eur. Polym. J. 2019, 120, 109224.

(6)      Chia-Jung Yu, Chen-Yu Li, Chen-Yen Tsai*, Bao-Tsan Ko*, “Titanium, zirconium and hafnium complexes bearing amino-benzotriazole phenolate ligands as efficient catalysts for ring-opening polymerization of lactides”, Inorg. Chem. Commun. 2019, 109, 107561.

(7)      Yu-Chia Su, Chen-Yen Tsai, Li-Shin Huang, Chia-Her Lin and Bao-Tsan Ko*, “Synthesis and characterization of di-nuclear bis(benzotriazole iminophenolate) cobalt complexes: catalysis for the copolymerization of carbon dioxide with epoxides”, Dalton Trans. 2019, 48, 12239–12249.

(8)      Fu-Yin Cheng, Chen-Yen Tsai*, Bor-Hunn Huang, Kuan-Yeh Lu, Chu-Chieh Lin* and Bao-Tsan Ko*, “Mono- and dinuclear copper complexes coordinated on NNO-tridentate Schiff-base derivatives for copolymerization of cyclohexene oxide and cyclic anhydrides”, Dalton Trans. 2019, 48, 4667–4676.

(9)      Wei-Yi Lu, Yung-Chi Chang, Cheng-Jie Lian, Kuo-Hui Wu, Michael Y. Chiang, Hsuan-Ying Chen*, Chu-Chieh Lin*, Bao-Tsan Ko*, “Optimization of six-membered ring aluminum complexes in ε-caprolactone polymerization”, Eur. Polym. J. 2019, 114, 151–163.

(10)  Yu-Chia Su, Wan-Ling Liu, Chen-Yu Li, Bao-Tsan Ko*, “Air-stable di-nuclear yttrium complexes as versatile catalysts for lactide polymerization and copolymerization of epoxides with carbon dioxide or phthalic anhydride”, Polymer 2019, 167, 21–30.

(11)  Yuan-Han Li, Sue-Lein Wang*, Yu-Chia Su, Bao-Tsan Ko*, Chen-Yen Tsai and Chia-Her Lin*, “Microporous 2D indium metal–organic frameworks for selective CO2 capture and their application in the catalytic CO2-cycloaddition of epoxides”, Dalton Trans. 2018, 47, 9474–9481.

(12)  Chi-Hang Chang, Chen-Yen Tsai, Wei-Jen Lin, Yu-Chia Su, Hui-Ju Chuang, Wan-Ling Liu, Chi-Tien Chen, Chih-Kuang Chen*, Bao-Tsan Ko*, “Alternating copolymerization of epoxides with carbon dioxide or cyclic anhydrides using bimetallic nickel and cobalt catalysts: Preparation of hydrophilic nanofibers from functionalized polyesters”, Polymer 2018, 141, 1–11.

(13)  Dei-Cheng Liu, Chen-Yu Li, Pei-Hua Lin, Jhy-Der Chen, Chen-Yen Tsai*, Chia-Her Lin*, Bao-Tsan Ko*, “Titanium complexes bearing benzotriazole iminophenolate ligands as efficient catalysts for ring-opening polymerization of cyclic esters”, Inorg. Chem. Commun. 2018, 90, 1–7.

(14)  Yi-Feng Lin*, Kai-Wei Huang, Bao-Tsan Ko*, Kun-Yi Andrew Lin, “Bifunctional ZIF-78 heterogeneous catalyst with dual Lewis acidic and basic sites for carbon dioxide fixation via cyclic carbonate synthesis”, J. CO2 Util., 2017, 22, 178–183.

(15)  Chen-Yu Li, Yu-Chia Su, Chia-Her Lin, Hsi-Ya Huang, Chen-Yen Tsai*, Ting-Yu Lee* and Bao-Tsan Ko*, “Synthesis and characterization of trimetallic cobalt, zinc and nickel complexes containing amine-bis(benzotriazole phenolate) ligands: efficient catalysts for coupling of carbon dioxide with epoxides”, Dalton Trans., 2017, 46, 15399–15406.

(16)  Li-Shin Huang, Chen-Yen Tsai, Hui-Ju Chuang, and Bao-Tsan Ko*, “Copolymerization of Carbon Dioxide with Epoxides Catalyzed by Structurally Well-Characterized Dinickel Bis(benzotriazole iminophenolate) Complexes: Influence of Carboxylate Ligands on the Catalytic Performance”, Inorg. Chem., 2017, 56, 61416151.

(17)  Zheng-Tang Liu, Chen-Yu Li, Jhy-Der Chen, Wan-Ling Liu, Chen-Yen Tsai*, Bao-Tsan Ko*, “Titanium, aluminum and zinc complexes containing diamine-bis(benzotriazole phenolate) ligands: Synthesis, structural characterization and catalytic studies for ring-opening polymerization of ε-caprolactone”, J. Mol. Struct., 2017, 1134, 395–403.

(18)  Bor-Hunn Huang, Chen-Yen Tsai, Chi-Tien Chen* and Bao-Tsan Ko*, “Metal complexes containing nitrogen-heterocycle based aryloxide or arylamido derivatives as discrete catalysts for ring-opening polymerization of cyclic esters”, Dalton Trans., 2016, 45, 17557–17580. (Invited Perspective)

(19)  Chen-Yen Tsai, Fu-Yin Cheng, Kuan-Yeh Lu, Jung-Tsu Wu, Bor-Hunn Huang, Wei-An Chen, Chu-Chieh Lin,* and Bao-Tsan Ko*,Dinuclear and Trinuclear Nickel Complexes as Effective Catalysts for Alternating Copolymerization on Carbon Dioxide and Cyclohexene Oxide”, Inorg. Chem. 2016, 55, 7843–7851.

(20)  Pei-Min Lin, Chi-Hang Chang, Hui-Ju Chuang, Cheng-Tang Liu, Bao-Tsan Ko*, and Chu-Chieh Lin*, “Bimetallic Nickel Complexes that Bear Diamine-Bis(Benzotriazole Phenolate) Derivatives as Efficient Catalysts for the Copolymerization of Carbon Dioxide with Epoxides”, ChemCatChem, 2016, 8, 984–991.

(21)  Chun-Yue Yu, Hui-Ju Chuang and Bao-Tsan Ko*, “Bimetallic bis(benzotriazole iminophenolate) cobalt, nickel and zinc complexes as versatile catalysts for coupling of carbon dioxide with epoxides and copolymerization of phthalic anhydride with cyclohexene oxide”, Catal. Sci. Technol., 2016, 6, 1779–1791.

(22)  Chin-Hsiang Chang, Hui-Ju Chuang, Ting-Yi Chen, Chen-Yu Li, Chia-Her Lin, Ting-Yu Lee, Bao-Tsan Ko*, Hsi-Ya Huang, “Di-Nuclear Zinc Complexes Containing Tridentate Imino-Benzotriazole Phenolate Derivatives as Efficient Catalysts for Ring-Opening Polymerization of Cyclic Esters and Copolymerization of Phthalic Anhydride with Cyclohexene Oxide”, J. Polym. Sci. Part A: Polym. Chem., 2016, 54, 714–725.

(23)  Jun-Han Wang, Chen-Yen Tsai, Jing-Kai Su, Bor-Hunn Huang,* Chu-Chieh Lin* and Bao-Tsan Ko*, “Mono-, di- and tetra-zinc complexes derived from an amino-benzotriazole phenolate ligand containing a bulkier N-alkyl pendant arm: synthesis, structure and catalysis for ring-opening polymerization of cyclic esters”, Dalton Trans., 2015, 44, 12401–12410.

(24)  Hui-Ju Chuang and Bao-Tsan Ko*, “Facilely synthesized benzotriazole phenolate zirconium complexes as versatile catalysts for copolymerization of carbon dioxide with cyclohexene oxide and lactide polymerization”, Dalton Trans., 2015, 44, 598–607.

(25)  Ching-Kai Su, Hui-Ju Chuang, Chen-Yu Li, Chun-Yue Yu, Bao-Tsan Ko*, Jhy-Der Chen and Ming-Jen Chen, “Oxo-Bridged Bimetallic Group 4 Complexes Bearing Amine-Bis(benzotriazole phenolate) Derivatives as Bifunctional Catalysts for Ring-Opening Polymerization of Lactide and Copolymerization of Carbon Dioxide with Cyclohexene Oxide”, Organometallics, 2014, 33, 70917100.

(26)  Cheng-You Wu, Duraisamy Senthil Raja, Chun-Chuen Yang,* Chun-Ting Yeh, Yu-Ru Chen, Chen-Yu Li, Bao-Tsan Ko* and Chia-Her Lin*Evaluation of structural transformation in 2D metal-organic frameworks based on 4,4'-sulfonyldibenzoate linker: microwave-assisted solvothermal synthesis, characterization and applicationsCrystEngComm, 2014, 16, 9308–9319.

(27)  Chi-Huan Li, Hui-Ju Chuang, Chen-Yu Li, Bao-Tsan Ko* and Chia-Her Lin “Bimetallic nickel and cobalt complexes as high-performance catalysts for copolymerization of carbon dioxide with cyclohexene oxidePolym. Chem., 2014, 5, 4875−4878.

(28)  Chen-Yen Tsai, Bor-Hunn Huang, Mon-Wei Hsiao, Chu-Chieh Lin* and Bao-Tsan Ko* “Structurally Diverse Copper Complexes Bearing NNO-Tridentate Schiff-Base Derivatives as Efficient Catalysts for Copolymerization of Carbon Dioxide and Cyclohexene Oxide” Inorg. Chem. 2014, 53, 5109−5116.

(29)  Chen-Yen Tsai, Hong-Cyuan Du, Jen-Chieh Chang, Bor-Hunn Huang, Bao-Tsan Ko* and Chu-Chieh Lin* “Ring-opening polymerization of cyclic esters initiated by zirconium, titanium and yttrium complexes” RSC Adv. 2014, 4, 14527–14537.

(30)  Hui-Ju Chuang, Ban-Hsin Wu, Chen-Yu Li and Bao-Tsan Ko* Benzotriazole Phenoxide Hafnium Complexes as Efficient Catalysts for the Ring-Opening Polymerization of Lactide: Synthesis, Characterization, and Kinetics of Polymerization Catalysis Eur. J. Inorg. Chem. 2014, 1239–1248.

(31)  Ting-Yi Chen, Chen-Yu Li, Chen-Yen Tsai, Chi-Huan Li, Chin-Hsiang Chang, Bao-Tsan Ko*, Ching-Yao Chang, Chia-Her Lin and Hsi-Ya Huang “Structurally well-characterized zinc complexes bearing imine-benzotriazole phenoxide ligands: Synthesis, photoluminescent properties and catalysis for carbon dioxide/epoxide coupling” J. Organomet. Chem. 2014, 754, 1625.

(32)  Chen-Yu Li, Dei-Cheng Liu and Bao-Tsan Ko* “Synthesis, characterization and reactivity of single-site aluminium amides bearing benzotriazole phenoxide ligands: catalysis for ring-opening polymerization of lactide and carbon dioxide/propylene oxide coupling” Dalton Trans. 2013, 42, 11488–11496.

(33)  Chao-Hsiang Wang, Chen-Yu Li, Bor-Hunn Huang,* Chu-Chieh Lin* and Bao-Tsan Ko* “Synthesis and structural determination of zinc complexes based on anilido-aldimine ligand containing O-donor pendant arm: Zinc alkoxide derivative as an efficient initiator for ring-opening polymerization of cyclic esters” Dalton Trans. 2013, 42, 10875–10884.

(34)  Chen-Yu Li, Shi-Jie Hsu, Chin-lung Lin, Chen-Yen Tsai, Jun-Han Wang, Bao-Tsan Ko*, Chia-Her Lin* and Hsi-Ya Huang “Air-Stable Copper Derivatives as Efficient Catalysts for Controlled Lactide Polymerization: Facile Synthesis and Characterization of Well-Defined Benzotriazole Phenoxide Copper Complexes” J. Polym. Sci. Part A: Polym. Chem. 2013, 51, 3840–3849.

(35)  Chen-Yu Li, Chia-Jung Yu, and Bao-Tsan Ko* Facile Synthesis of Well-Defined Titanium Alkoxides Based on Benzotriazole Phenoxide Ligands: Efficient Catalysts for Ring-Opening Polymerization of Cyclic Esters” Organometallics 2013, 32, 172180.

(36)  Tsai-Ming Chung, Hsiao-Fang Wang, Tao Lin, Yeo-Wan Chiang*, Yi-Chun Chen, Bao-Tsan Ko*, and Rong-Ming Ho* “Helical Phase Driven by Solvent Evaporation in Self-Assembly of Poly(4-vinylpyridine)-block-poly(L-lactide) Chiral Block Copolymers” Macromolecules 2012, 45, 97279733.

(37)  Wan-Ju Tai, Chen-Yu Li, Pei-Hua Lin, Jia-Ying Li, Ming-Jen Chen*, Bao-Tsan Ko* “Synthesis and characterization of aluminum complexes based on amino-benzotriazole  phenoxide  ligand: luminescent properties and catalysis for ring-opening polymerization” Appl. Organometal. Chem. 2012, 26, 518–527.

(38)  Chen-Yu Li, Chen-Ruei Wu, Yi-Chang Liu, Bao-Tsan Ko* Trimetallic magnesium complexes bearing amine-bis(benzotriazole phenolate) derivatives as bifunctional catalysts for ring-opening polymerization and CO2/epoxide coupling Chem. Commun. 2012, 48, 9628–9630.

(39)  Bao-Tsan Ko*, Chia-Chih Chang, Shu-Ling Lai, Fun-Jie Lai, Chu-Chieh Lin*, Syntheses, structures and DNA cleavage activity of NNO-tridentate Schiff base copper complexesPolyhedron 2012, 45, 49–54.

(40)  Chen-Yu Li, Po-Sheng Chen, Shi-Jie Hsu, Chia-Her Lin, Hsi-Ya Huang, Bao-Tsan Ko* “Mono-aluminum, di-magnesium and tri-zinc complexes supported by bisphenolate ligand: Synthesis, characterization and catalytic studies for ring-opening polymerization of cyclic esters” J. Organomet. Chem. 2012, 716, 175181.

(41)  Chen-Yu Li, Jing-Kai Su, Chia-Jung Yu, Yu-En Tai, Chia-Her Lin, Bao-Tsan Ko* “Synthesis and structural characterization of magnesium complexes bearing benzotriazole phenoxide ligands: Photoluminescent properties and catalytic studies for ring-opening polymerization of L-lactide Inorg. Chem. Commun. 2012, 20, 6065.

(42)  Chang-Yu Sung, Chen-Yu Li, Jing-Kai Su, Ting-Yi Chen, Chia-Her Lin and Bao-Tsan Ko* “Zinc and magnesium complexes incorporated by bis(amine) benzotriazole phenoxide ligand: Synthesis, characterization, photoluminescent properties and catalysis for ring-opening polymerization of lactide Dalton Trans. 2012, 41, 953961.

(43)  Yu-En Tai, Chen-Yu Li, Chia-Her Lin, Yi-Chang Liu, Bao-Tsan Ko*, Ya-Sen Sun “Efficient Catalysts for Ring-Opening Polymerization of ε-Caprolactone and β-Butyrolactone: Synthesis and Characterization of Zinc Complexes Based on Benzotriazole Phenoxide Ligands” J. Polym. Sci. Part A: Polym. Chem. 2011, 49, 4027–4036.

(44)  Chao-Hsiang Wang, Chen-Yu Li, Chia-Her Lin, Yi-Chang Liu, Bao-Tsan Ko* “Reactions of (E)-N-[2-(benzyliminomethyl)phenyl]- 2,6-diisopropylaniline with diethylzinc: Synthesis, characterization and catalytic studies for ring-opening polymerization of ε-caprolactone Inorg. Chem. Commun. 2011, 14, 1456–1460.

(45)  Jia-Ying Li, Chen-Yu Li, Wan-Ju Tai, Chia-Her Lin*, Bao-Tsan Ko* “Synthesis and structural characterization of zinc complexes supported by amino-benzotriazole phenoxide ligands: Efficient catalysts for ring-opening polymerization of ε-caprolactone and β-butyrolactone Inorg. Chem. Commun. 2011, 14, 1140–1144.

(46)  Chen-Yen Tsai, Chen-Yu Li, Chia-Her Lin, Bor-Hunn Huang, Bao-Tsan Ko* “Reactions of 4-methylidene-bis(1-phenyl-3-methylpyrazol- 5-one) with trimethylaluminum: Synthesis, structure and catalysis for the ring-opening polymerization of ε-caprolactoneInorg. Chem. Commun. 2011, 14, 271–275.

(47)  Chen-Yu Li, Chen-Yen Tsai, Chia-Her Lin and Bao-Tsan Ko* “Synthesis, structural characterization and reactivity of aluminium complexes supported by benzotriazole phenoxide ligands: air-stable alumoxane as an efficient catalyst for ring-opening polymerization of L-lactide Dalton Trans. 2011, 40, 18801887.

(48)  Yi-Chung Liu, Chia-Her Lin, Bao-Tsan Ko*, Rong-Ming HoRing-Opening Polymerization of β-Butyrolactone Catalyzed by Efficient Magnesium and Zinc Complexes Derived from Tridentate Anilido-Aldimine Ligand” J. Polym. Sci. Part A: Polym. Chem., 2010, 48, 53395347.

(49)  Po-Sheng Chen, Yi-Chung Liu, Chia-Her Lin, Bao-Tsan Ko*Magnesium Complexes Incorporated by Sulfonate Phenoxide Ligands as Efficient Catalysts for Ring-Opening Polymerization of e-Caprolactone and Trimethylene CarbonateJ. Polym. Sci. Part A: Polym. Chem., 2010, 48, 3564–3572.

(50)  Yueh-Hsuan Tsai, Chia-Her Lin, Chu-Chieh Lin*, Bao-Tsan Ko*Tridentate Anilido-Aldimine Magnesium and Zinc Complexes as Efficient Catalysts for Ring-Opening Polymerization of ε-Caprolactone and L-LactideJ. Polym. Sci. Part A: Polym. Chem., 2009, 47, 4927–4936.

(51)  Chih-Ping Chen, Shu-Hua Chan, Teng-Chih Chao, Ching Ting* and Bao-Tsan Ko* “Low-Bandgap Poly(Thiophene-Phenylene-Thiophene) Derivatives with Broaden Absorption Spectra for Use in High-Performance Bulk-heterojunction Polymer Solar Cells” J. Am. Chem. Soc. 2008, 130, 1282812833.

(52)  Shu-Hua Chan, Chih-Ping Chen, Teng-Chih Chao, Ching Ting, Chin-Sheng Lin and Bao-Tsan Ko* “Synthesis, Characterization and Photovoltaic Properties of Novel Semiconducting Polymers with Thiophene-Phenylene-Thiophene (TPT) as Coplanar Units” Macromolecules 2008, 41, 55195526.