|
ªL¬f¦ë Po-Heng Lin |
µL¾÷¤Æ¾Ç Inorganic Chemistry ³æ¤À¤lºÏÅK¡AºÏ©Ê§÷®Æ¡AùS¨t¤Æ¦Xª«¦X¦¨ Single Molecule Magnets (SMMs), Magnetic material, Syntheses of Pure Lanthanide
Complexes |
l Professor, National Chung Hsing University (2021/2~) l Assistant Professor, National Chung Hsing University (2018/8~2021/2) l Assistant Professor, National Chung Hsing
University
(2014/8~2018/8) l Postdoctoral, Division
of Chemistry and Chemical Engineering, California Institute of Technology,
USA
(2012/9~2014/7) l Ph. D., Department of Chemistry, University of Ottawa, Canada (2007/1~2012/8) l °ê¥ß²MµØ¤j¾Çì¤l¬ì¾Ç¨tºÓ¤h (2002/6~2004/6) l °ê¥ß¤¤¥¿¤j¾Ç¤Æ¾Ç¨t¾Ç¤h (1998/09~2002/6) l ¥x¥_¥«¥ß¦¨¥\°ª¤¤ (1995/9~1998/06) |
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Single
Molecule Magnets (SMMs) display characteristic slow relaxation of the
magnetization at low temperatures and have the potential to store one bit of
information on each molecule. These novel magnetic materials have been widely
studied, particularly for the next generation computers. Our research focuses
on the design and synthesis of pure lanthanide metal clusters with record
energy barriers for this application. Moreover, we are also interested in
understanding how to self-assemble the lanthanide metal clusters logically in
order to further discover novel molecular materials. |
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´Á¥Z½×¤å 1.
Che-Jung
Kuo, Rebecca J. Holmberg, Po-Heng
Lin*, ¡§Slight Synthetic Changes Eliciting Different Topologies:
Synthesis, Structure and Magnetic Properties of Novel Dinuclear and
Nonanuclear Dysprosium Complexes.¡¨ Dalton
Trans., 2015, 44, 19758. 2.
Po-Heng Lin, Michael K. Takase, Theodor Agapie*,
¡§Investigations of the Effect of the Non-Manganese Metal in
Heterometallic-Oxido Cluster Models of the Oxygen Evolving Complex of
Photosystem II: Lanthanides as Substitutes for Calcium.¡¨ Inorg. Chem., 2015, 54, 59. 3.
Jacob
S. Kanady, Po-Heng Lin,
Kurtis M. Carsch, Robert J. Nielsen, Michael K. Takase, William A. Goddard,
III, Theodor Agapie, ¡§Toward Models for the Full Oxygen-Evolving Complex of
Photosystem II by Ligand Coordination To Lower the Symmetry of the
Mn3CaO4Cubane: Demonstration That Electronic Effects Facilitate Binding of a
Fifth Metal¡¨ J. Am. Chem. Soc., 2014, 136, 14373. 4.
Jianguo
Wu, Gray W. Brudvig, Wei Dai, Louise M. Guard, Nilay Hazari*, Po-Heng Lin, Ravi Pokhrel and
Michael K. Takase, ¡§Nickel(I) Monomers and Dimers with Cyclopentadienyl and
Indenyl Ligands.¡¨ Chem. Eur. J., 2014, 20, 5327. 5.
Wen-Bin Sun, Bing-Lu Han, Po-Heng Lin, Hong-Feng Li, Peng
Chen, Yong-Mei Tian, Muralee, Murugesu* and Peng-Fei Yan*, ¡§Series of
Dinuclear and Tetranuclear Lanthanide Clusters Encapsulated by Salen-Type and
£]-Diketionate Lignads: Single-Molecule Magnet
and Fluorescence Properties.¡¨ Dalton Trans., 2013, 42, 13397. 6.
Po-Heng Lin, Ilia Korobkov, Tara J. Burchell, Muralee
Murugesu,* ¡§Connecting Single-Ion Magnets through Ligand
Dimerisation.¡¨ Dalton Trans., 2012, 41, 13649. 7.
Po-Heng Lin, Wen-Bin Sun,* Yong-Mei Tian, Peng-Fei
Yan,* Liviu Ungur, Liviu F. Chibotaru,* Muralee Murugesu,* ¡§Ytterbium can relax
slowly too: a field-induced Yb2
single-molecule magnet.¡¨ Dalton Trans., 2012, 41, 12349. 8.
Fatemah Habib, Jérôme Long, Po-Heng Lin, Ilia Korobkov, Liviu Ungur, Liviu F.
Chibotaru, Muralee Murugesu,* ¡§Supramolecular architectures for controlling slow magnetic
relaxation in field-induced single-molecule magnets.¡¨ Chem. Sci.,
2012, 3, 2158. 9.
R.
Thomas Baker*, John C. Gordon*, Charles W. Hamilton,
Neil J. Henson, Po-Heng Lin,
Muralee Murugesu, Brian L. Scott and Nathan C. Smythe, ¡§Iron Complex-Catalyzed Ammonia-Borane Dehydrogenation. A Potential Route
towards B-N Containing Polymer Motifs Using Earth Abundant Metal
Catalysts.¡¨ J. Am. Chem. Soc., 2012,
134, 5598. 10.
Matthew
Jeletic, Po-Heng Lin,
Jennifer J. Le Roy, Ilia Korobkov, Muralee Murugesu,* ¡§An Organometallic
Sandwich Lanthanide Single-Molecule Magnet with an Unusual Multiple
Relaxation Mechanism.¡¨ J. Am. Chem.
Soc., 2011, 133, 19286. 11.
Po-Heng Lin, Nathan C. Smythe, Serge Gorelsky, Steven
Maguire, Neil J. Henson, Ilia Korobkov, Brian L. Scott, John C. Gordon, R.
Tom Baker, Muralee Murugesu*, ¡§Importance of Out-of-State Spin-Orbit Coupling
for Slow Magnetic Relaxation in Mono-nuclear FeII complexes.¡¨ J. Am. Chem. Soc., 2011, 133, 15806. 12.
Titel
Jurca, Ahmed Farghal, Po-Heng Lin,
Ilia Korobkov, Muralee Murugesu*, Darrin S. Richeson,* ¡§Single-Molecule
Magnet Behavior with a Single Metal Center Enhanced through Peripheral Ligand
Modifications¡¨ J. Am. Chem. Soc., 2011, 133,
15814. 13.
Po-Heng Lin, Wen-Bin Sun,* Mang-Fei Yu, Guang-Ming Li, and Peng-Fei Yan,* Muralee Murugesu,* ¡§An Unsymmetrical Coordination
Environment Leading to Two Slow Relaxation Modes in Dy2
Single-Molecule Magnet.¡¨ Chem. Commun.,
2011, 47, 10993. 14.
Peng-Fei
Yan, Po-Heng Lin, Fatemah
Habib, Tomoko Aharen, Muralee Murugesu,* Zhao-Peng Deng, Guang-Ming Li, Wen-Bin Sun*, ¡§Planar Tetranuclear Dy(III) Single-Molecule Magnet and Its Sm(III),
Gd(III) and Tb(III) Analogues Encapsulated By Salen-Type and £]-Diketonate
Ligands.¡¨ Inorg. Chem., 2011, 50, 7059. 15.
Po-Heng Lin, Sarah Eastman, Aman Bhatti, Melanie
Brulotte, Tara J. Burchell, Ilia Korobkov, Gary Enright, Rodolphe Clérac and
Muralee Murugesu*, ¡§Polyalcohol Ligands in CuII and FeIII
Cluster Chemistry: Synthesis, Structures and Magnetic Properties of {Cu12}
and {Fe8} Aggregates.¡¨ Inorg.
Chim. Acta., 2011, 375, 187. 16.
Fatemah
Habib, Po-Heng Lin, Jérôme
Long, Ilia Korobkov, Wolfgang Wernsdorfer and Muralee Murugesu*, ¡§The Use of
Magnetic Dilution to Elucidate the Slow Magnetic Relaxation Effects of a Dy2
Single-Molecule Magnet¡¨ J. Am. Chem.
Soc., 2011, 133, 8830. 17.
Derek J. Reid, John E. W. Cull, Kimberley D. S.
Chisholm, Alexandre Langlois, Po-Heng
Lin, Jérôme Long, Olivier Lebel, Ilia Korobkov, Ruiyao Wang, James D.
Wuest, Muralee Murugesu and Jennifer Scott*, ¡§Synthesis,
Structure and Magnetism of Homodinuclear Complexes of Co, Ni and Cu Supported
by a Novel Bitriazine Scaffold.¡¨ Dalton Trans., 2011, 40, 5009. 18.
Po-Heng Lin, Ilia Korobkov, Wolfgang Wernsdorfer,
Liviu Ungur, Liviu F. Chibotaru and Muralee Murugesu*, ¡§A Rare £g4-O
Centred Dy4 Tetrahedron with Coordination-Induced Local Chirality
and Single-Molecule Magnet Behaviour.¡¨ Eur.
J. Inorg. Chem., 2011, 2011, 1535. 19.
Jérôme
Long, Fatemah
Habib, Po-Heng Lin, Ilia Korobkov, Gary Enright, Liviu Ungur,
Wolfgang Wernsdorfer, Liviu F. Chibotaru and Muralee Murugesu*, ¡§Single-Molecule Magnet Behavior for an Antiferromagnetically
Superexchange-Coupled a Dinuclear Dysprosium(III)
Complex.¡¨ J. Am. Chem. Soc., 2011, 133, 5319. 20.
Po-Heng Lin, Serge
Gorelsky, Didier Savard, Tara J. Burchell, Wolfgang Wernsdorfer, Rodolphe
Clérac and Muralee Murugesu*, ¡§Synthesis, Characterisation and Computational
Studies on a Novel One-Dimensional Arrangement of Schiff-base Mn3
Single-Molecule Magnet.¡¨ Dalton Trans., 2010, 39, 7650. 21.
Po-Heng Lin, Mathieu Leclère, Jérôme Long, Tara J. Burchell, Ilia
Korobkov, Rodolphe Clérac and Muralee Murugesu*, ¡§Fluorescent Dialdehyde Ligand
for the Encapsulation of Dinuclear Luminescent Lanthanide Complexes.¡¨ Dalton Trans., 2010, 39, 5698. 22.
Po-Heng Lin, Tara J. Burchell, Liviu Ungur, Liviu
Chibotaru, Wolfgang Wernsdorfer and Muralee Murugesu*, ¡§A Polynuclear
Lanthanide Single-Molecule Magnet with a Record Anisotropic Barrier.¡¨ Angew.
Chem. Int. Ed., 2009, 48,
9489. 23.
Didier
Savard, Po-Heng Lin, Tara
J. Burchell, Wolfgang Wernsdorfer, Rodolphe Clérac and Muralee Murugesu*,
¡§Two-Dimensional Networks of Lanthanide Cubane-Shaped Dumbbells.¡¨ Inorg. Chem., 2009, 48, 11748. 24.
Carolyn
E. Burrow, Tara J. Burchell, Po-Heng
Lin, Fatemah Habib, Wolfgang Wernsdorfer, Rodolphe Clérac and Muralee
Murugesu*, ¡§Salen-Based [Zn2Ln3] Complexes with
Fluorescence and Single Molecule Magnet Properties,¡¨ Inorg. Chem., 2009,
48, 8051. 25.
Po-Heng Lin, Tara J. Burchell, Rodolphe Clérac* and
Muralee Murugesu*, ¡§Dinuclear Dysprosium(III) Single-Molecule Magnets with a
Large Anisotropic Barrier.¡¨ Angew.
Chem. Int. Ed., 2008, 47, 8848. |