有機及材料化學 

 葉鎮宇 (Chen-Yu Yeh)

Organic and Material Chemistry

 

學 經 歷

1.

B. S., Chemistry, National Chung-Hsing Unversity (1986-1990)

 Experience

2.

M.S., Chemistry, National Taiwan University (1990-1992)

 

3.

Ph.D., Chemistry, Michigan State University (1995-1999)

 

4.

Postdoctoral Fellow, Chemistry, Massachusetts Institute of Technology (1999-2000)

 

5.

Postdoctoral Fellow, Chemistry, National Taiwan University (2000-2002)

 

6.

Assistant Professor, National Chung-Hsing University (2002-)

 

7

Associate Professor, National Chung-Hsing Univeristy (2006-)

通 訊 處
Contact Info.

 

 886-4-22840411 ext. 610, cyyeh@dragon.nchu.edu.tw

Personal HomePage

 

 

 

研究興趣
本實驗室主要研究方向包括紫質化學所有領域，特別是可用來當催化劑、感應器、及藥物之系統的設計與研究。以下是主要的研究主題：

(1)用於形狀選擇和非對稱氧化反應之紫質催化劑合成。
(2)用於分子辨識之官能化紫質合成。
(3)用於建構超分子之具有氫鍵的紫質合成。
(4) 用於光動力學藥物之紫質感光劑之合成。

 

 

 

Research Interests
Our research interests focus on all aspects of the porphyrin chemistry, and especially on the design and study of the systems that can be used as catalysts, sensors, and drugs.
The following topics are currently under investigation in our laboratory:
(1) The synthesis of porphyrin catalysts for the use of shape-selective and asymmetrical oxidation catalysis.
(2) The synthesis of functionalized porphyrins for molecular recognition.
(3) The synthesis of porphyrins functionalized with hydrogen-bond synthons for the construction of supramolecules.
(4) The synthesis of porphyrin-based photosensitizers as photodynamic drugs.

Selected Publications:

 

l           Yi-Jen Chen, Szu-Shuo Chen, Shang-Shih Lo, Teng-Hui Huang, Chen-Chang Wu, Gene-Hsiang Lee, Shie-Ming Peng and Chen-Yu Yeh*, “Porphyrin Dimers Bridged by a Platinum-diacetylide Unit”, Chem. Commun., 2006, 1015.

l           Teng-Hui Huang, Yi-Jen Chen, Shang-Shih Lo, Wei-Nan Yen, Chi-Lun Mai, Ming-Cheng Kuo and Chen-Yu Yeh*, “Highly conjugated multiporphyrins: synthesis, and spectroscopic and electrochemical properties”, Dalton Trans., 2006, In press.

l           Chih-Hsien Chien, Jung-Che Chang, Chen-Yu Yeh*, Gene-Hsiang Lee, Jim-Min Fang and Shie-Ming Peng*, “Novel linear hexanuclear cobalt string complexes (Co612+) and one-electron reduction products (Co611+) supported by four bpyany2– ligands”, Dalton Trans., 2006, In press.

l           Chen-Yu Yeh, Chih-ChiehWang, Chun-Hsien Chen and Shie-Ming Peng, “Nano Redox Sites: Nano-Space Control and Its Applications”, Chapter 5 (Molecular Metal Wires Built from a Linear Metal Atom Chain Supported by Oligopyridylamido Ligands), Springer, 2006, In press.

l           Jung-Che Chang, Chi-Juan Ma, Gene-Hsiang Lee, Shie-Ming Peng and Chen-Yu Yeh*, “Porphyrin-triarylamine conjugates: strong electronic communication between triarylamine redox centers via the porphyrin dication”, Dalton Trans., 2005, 1504.

l           Yi-Jen Chen, Gene-Hsiang Lee, Shie-Ming and Chen-Yu Yeh*, “Unexpected formation of porphyrinic enyne under Sonogashira conditions”, Tetrahedron Lett., 2005, 3265.

l           Ching-Kuo Kuo, Jung-Che Chang, Chen-Yu Yeh*, Gene-Hsiang Lee, Chih-Chieh Wang and Shie-Ming Peng*, ” Synthesis, structures, magnetism and electrochemical properties of triruthenium–acetylide complexes”, Dalton Trans., 2005, 3696.

l           Zhi-Kai Chan, Ying-Yann Wu, Jhy-Der Chen*, Chen-Yu Yeh, Chih-Chieh Wang, Yi-Fang Tsai and Ju-Chun Wang, “Linear and cyclic tetranuclear copper(I) complexes containing anions of N,N'-bis(pyrimidine-2-yl)formamidine”, Dalton Trans., 2005, 985.

l           麥綺倫, 葉鎮宇 “不對稱金屬紫質的催化反應”, 化學 (中國化學會), 2005, 63, 529.

l           Shu-Li Lin, I-Wen Chen, Chun-hsien Chen, Ming-Hsun Hsieh, Chen-Yu Yeh, Tzu-Wei Lin, Yu-Hua Chen and Shie-Ming Peng*, “Effect of Metal-Metal Interactions on Electron Transfer: an STM Study of One-Dimensional Metal String Complexes” J. Phys. Chems. B, 2004, 959.

l           Ting-Bin Tsao, Gene-Hsiang Lee, Chen-Yu Yeh and Shie-Ming Peng*, “Supramolecular assembly of linear trinickel complexes incorporating metalloporphyrins: a novel one-dimensional polymer and oligomer” Dalton Trans., 2003, 1465.

l          Chen-Yu Yeh, Chung-Hsien Chou, Kun-Chih Pan, Chih-Chieh Wang, Gene-Hsiang Lee, Y. Oliver Su and Shie-Ming Peng, “Linear Pentacobalt Complexes: Synthesis, Structures, and Physical Properties of Both Neutral and One-electron Oxidation Compounds” J. Chem. Soc. Dalton 2002, 13, 2670.

l          Chen-Yu Yeh, Yi-Li Chiang, Gene-Hsiang Lee and Shie-Ming Peng, “Unsymmetrical Linear Pentanuclear Nickel String Complexes: [Ni5(tpda)4(H2O)(BF4)](BF4)2 and [Ni5(tpda)4(SO3CF3)2](SO3CF3)” Inorg. Chem. 2002, 41, 4096.

l          Christopher J. Chang, Yongqi Deng, Shie-Ming Peng, Gene-Hsiang Lee, Chen-Yu Yeh and Daniel G. Nocera, “A Convergent Synthetic Approach Using Sterically Demanding Aryl-dipyrrylmethanes for Tuning the Pocket Sizes of Cofacial Bisporphyrins” Inorg. Chem. 2002, 41, 3008.

l          Christopher J. Chang, Chen-Yu Yeh and Daniel G. Nocera, “Porphyrin Architectures Bearing Functionalized Xanthene Spacers” J. Org. Chem. 2002, 67, 1403.

l          Chen-Yu Yeh, Christopher J. Chang and Daniel G. Nocera, “Hangman Porphyrins for the Assembly of a Model Heme Water Channel” J. Am. Chem. Soc. 2001, 123, 1513.

l          Chen-Yu Yeh, Scott E. Miller, Scott D. Carpenter and Daniel G. Nocera, “Structurally Homologous β- and Meso-Amidinium Porphyrins” Inorg. Chem. 2001, 40, 3643. 

l          Chi K. Chang, Chen-Yu Yeh and Tat-Shing Lai, “Synthesis of Sterically Encumbered Porphyrins as Catalysts for Shape-Selective Oxidations” Macromolecular Symposia, 2000, 156, 117.